Reagents for transition metal complex and organometallic syntheses

  • New York : Wiley c1990
Physical description
1 online resource (491 p.)
  • 1-282-30534-4
  • 9786612305344
  • 0-470-13259-0
  • 0-470-13294-9
  • "A Wiley-Interscience publication."
  • "This volume is dedicated to Professor Fred Basolo on the occasion of his 70th birthday."--p. [v].
  • Includes bibliographical references and indexes.
  • English
  • INORGANIC SYNTHESES; CONTENTS; Chapter One COMPLEXES WITH WEAKLY COORDINATED LIGANDS; 1. Metal Complexes with Weakly Bonded Anions: General Considerations; 2. Carbony(n5 -cyclopentadienyl)(tetrafluoroborato)molybdenum and -tungsten complexes: CpM (CO)2(L) (BF4) (M = Mo, W; L = CO, PPh3); A. Tricarbonyl(n5-cyclopentadienyl) (tetrafluoroborato) molybdenum and -tungsten; B. Dicarbonyl(n5-cyclopentadienyl)(tetrafluoroborato)(triphenylphosphine)molybdenum and -tungsten, MCp(CO)2(PPh3)(FBF3) (M = Mo, W); C. Tricarbonyl(n5-cyclopentadienyl(n2-ethene)molybdenum (1 + ) Tetrafluoroborate(1 - )
  • D. Carbonyl(n5-cyclopentadienyl)bis(diphenylene) molybdenum (1 + ) Tetrafluoroborate(1 -)E. Carbonyl(n5-cyclopentadienyl)(diphenylacetylene) (triphenylphosphine) molybdenum(1 + ) Tetrafluoroborate(1 - ); F. (Acetone)(tricarbonyl)(n5-cyclopentadienyl)molybdenum- (1 + ) and -tungsten(l + ) Tetrafluoroborate(1 - ); 3. Pentacarbonyl(tetrafluoroborato)rhenium and -manganese and Reactions Thereof: M(CO)5(BF4) (M = Mn, Re); A. Pentacarbonylmethylrhenium: Re(CO)5Me; B. Pentacarbonyl(tetrafluoroborato)rhenium(I); C. Pentacarbonyl(n2-ethene)rhenium(1 + ) Tetrafluoro-borate(1 - ): Re(CO)5(n2-C2H4)+
  • D. Octadecacarbonyl-bis(u3-carbon dioxide)-tetrarhenium: Re4(CO)18(CO2)24. Iridium(III) Complexes with the Weakly Bonded Anions [BF4-] and [OSO2CF33-]; A. Carbonylcholrohydrido(tetrafluoroborato)bis(tri-phenylphosphine)iridium(III): tr(Cl)(CO)(PPh3)2(H)(BF4); B. Carbonylchloromethyl(tetrafluoroborato)bis(triphenylphos-phine)iridium(III): Ir(Cl)(CO)(PPh3)2(CH3)(BF4); C. Chloro(dinitrogen)hydrido(tetrafluoroborato)bis(triphenyl-phosphine)iridium(III): Ir(Cl)(N2)(PPh3)2(H)(BF4); D. Carbonylhydridobis(trifluoromethanesulfonato)bis(tri-phenylphosphine)iridium(III): Ir(CO)(PPh3)2(H)(O3SCF3)2
  • 5. cis-Chlorobis(triethylphosphine)(trifluoromethanesulnato)-platinum(II)6. Tricarbonyltris(nitrile) Complexes of Cr, Mo, and W: M(CO)3(NCEt)3 (M = Cr, Mo, W); A. Tricarbonyltris(propionitrile)tungsten(0); B. Tricarbonyltris(propionitrile)molybdenum(0); C. Tricarbonyltris(propionitrile)chromium(0); 7. The Synthesis of Molybdenum and Tungsten Dinitrogen Com-plexes: MoCl4(L)2, MoCl3(L)3 (L = NCMe, THF), Mo(N2)2(dppe)2, W(N2)2(dppe)2; A. Bis(acetonitrile)tetrachloromolybdenum(IV), [MoCl4(CH3CN)2]; B. Tetrachlorobis(tetrahydrofuran)molybdenum(IV), [MoCl4(THF)2]
  • C. Trichlorotris(tetrahydrofuran)molybdenum(III), [MoCl3(THF)3]D. Trichlorotris(acetonitrile)molybdenum(III), [MoCl3(MeCN3]; E. trans-Bis(dinitrogen)bis[1,2-ethanediylbis-[1,2-ethanediylbis-(biphenylphosphine)]milybdenum(0), trans-[Mo(N2)2(Ph2PCH2CH2PPh2)2]; F. Tetrachlorobis(triphenylphosphine)tungsten(IV), [WCl4(PPh3)2]; G. Tetrachloro[1,2-ethanediylbis(diphenyl-phosphine)]tungsten(IV), [WCl4(Ph2PCH2CH2PPh2)]; H. trans-Bis(dinitrogen)-bis[1,2-ethanediylbis(diphenylphosphine)]tungston(0), trans-[W(N2)2(Ph2PCH2CH2PPh2)2]
  • 8. trans-Bis[1,2-ethanediylbis(diphenylphosphine)]bis-(isocyanomethane)tungsten(0): trans-
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  • The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

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